HFC-227ea MSDS

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WAYSMOS USA INC 12001 Oak Knoll Dr Suite 8 Austin, TX 78759 646-593-8882
Fire Extinguishing Agent WAYSMOS
HFC-227ea MSDS
Chemical Name: 1,1,1,2,3,3,3-Heptafluoropropane
SECTION I – PRODUCT AND MANUFACTURER INFORMATION
TRADE NAME / LABEL NAME MH227 , HFC-227ea
CAS NUMBER 431890
CHEMICAL FAMILY Halogenated alkane; Hydrofluorocarbon
CHEMICAL NAME 1,1,1,2,3,3,3-Heptafluoropropane
SYNONYMS 2H-Heptafluoropropane; HFC-227ea;
MANUFACTURER’S NAME WAYSMOS USA
MANUFACTURER’S ADDRESS 12001 Oak Knoll Dr, Suite 8, Austin, Texas 78759
PHONE 800-633-8253, If outside USA call +1 801-629-0667
FASCIMILE +86-21-58162299
DATE OF PREPARATION June 16, 2016
PRODUCT USE Fire/explosion extinguishing, suppression and prevention (inerting) agent for use in total flooding systems or portable extinguishers. THIS PRODUCT IS NOT SUITABLE FOR USE AS AN ACTIVE PHARMACEUTICAL INGREDIENT, PHARMACEUTICAL EXCIPIENT OR DOSAGE AGENT.
SECTION II – COMPOSITION AND INGREDIENT INFORMATION
CHEMICAL NAME 1,1,1,2,3,3,3-Heptafluoropropane
CAS Number 431890
% w/w > 99.9
OSHA PEL TWA mg/m3 Not established
OSHA PEL STEL mg/m3 Not established
OSHA PEL CEIL mg/m3 Not established
ACGIH TLV TWA mg/m3 Not established
ACGIH TLV STEL mg/m3 Not established
ACGIH TLV CEIL mg/m3 Not established
TOXICITY DATA N/A
SECTION III – PHYSICAL AND CHEMICAL CHARACTERISTICS
GENERAL Colorless, odorless gas
BOILING POINT -16.4°C / 3°F
VAPOR PRESSURE(@ 21°C / 70°F) 58.8 psia
VAPOR DENSITY(AIR =1) 6.04
WATER REACTIVE NO
SPECIFIC GRAVITY (H2O =1) 1.46
PERCENT VOLATILE BY VOLUME N/A
EVAPORATION RATE(Butyl acetate = 1) N/A
VISCOSITY(@ 20°C / 68°F) N/A
MELTING POINT -131°C / -204°F
WATER SOLUBILITY (v/v @ 20°C / 68°F) 260 mg/L
SECTION IV – FIRE AND EXPLOSION HAZARDS
FLASH POINT N/A
FLAMMABLE LIMIT (in air; % by volume) N/A
AUTO-IGNITION TEMPERATURE N/A
EXTINGUISHING MEDIA All are suitable. While product is non-flammable and extinguishes fires at sufficient concentration, can undergo thermal decomposition if involved in fires where quantity of product is insufficient to extinguish. Thermal decomposition products may be toxic or corrosive.
UNUSUAL FIRE AND EXPLOSION HAZARDS Container rupture possible if pressure and temperature relief valves should fail.
SPECIAL FIRE FIGHTING PROCEDURES Employ water spray from a safe distance to prevent container rupture. If containers should rupture, use self contained breathing apparatus. Product is non-flammable, but denser than air, posing asphyxiation risk. Thoroughly ventilate affected area to remove product and any decomposition products before allowing re-entry.
SECTION V – REACTIVITY DATA
STABILITY Stable
CONDITIONS TO AVOID N/A
HAZARDOUS POLYMERIZATION N/A
INCOMPATIBLE MATERIALS Powdered metals such as aluminum, magnesium or zinc; strong alkaline agents; oxidizing agents; reducing agents.
HAZARDOUS DECOMPOSTION PRODUCTS Thermal decomposition products may include hydrogen fluoride, carbon monoxide and carbon dioxide.
SECTION VI – HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE N/A
POTENTIAL EXPOSURE ROUTES Inhalation – Yes Eye contact – Yes Skin contact – Yes Ingestion – No
SIGNS AND SYMPTOMS OF OVEREXPOSURE Inhalation of excessive concentrations in air may induce symptoms of hypoxia (headache, nausea, dizziness, loss of consciousness) or cardiac sensitization (irregular pulse or arrhythmia). Product is a cryogenic gas. Direct skin contact at point of release may cause symptoms of frostbite due to evaporative cooling (cold, white, discolored skin that, in severe cases, may exhibit blistering).
MEDICAL CONDITIONS POTENTIALLY AGGRAVATED BY EXPOSURE Pre-existing cardiac, respiratory or CNS disorders may be exacerbated by overexposure. Epinephrine or sympathomemetic drugs may increase susceptibility to cardiac irregularities upon overexposure.
CARCINOGENICITY NTP Program – No IARC Monographs – No OSHA – No ACGIH – No Other – No
MUTAGENICITY S. typhimurium assay – No Mouse lymphoma assay – No Mouse micronuclei assay – No
LC50 > 800,000 ppm
EMERGENCY AND FIRST AID PROCEDURES Inhalation – Move to fresh air. Artificial respiration if not breathing. Administer oxygen if breathing is labored. Seek medical attention. Eye contact – Flush/irrigate with fresh water. Seek medical attention. Skin contact – Flush/irrigate (spray) with water. Apply sterile dressing as necessary. Seek medical treatment for symptoms of frostbite. Ingestion – N/A NOTE TO PHYSICIANS: In treating cases of overexposure through inhalation, use of epinephrine, sympathomemetics or other stimulants is contraindicated as such compounds increase susceptibility to cardiac sensitization (irregular pulse or arrhythmia).
SECTION VII – SPILL/LEAK PROCEDURES AND SPECIAL PRECAUTIONS
HANDLING AND STORAGE PRECAUTIONS Store in a cool, dry, well-ventilated area separate from incompatible materials. Protect containers from mechanical damage. Follow fire equipment manufacturer’s instructions for operation, inspection, maintenance and repair of portable extinguishers and fixed extinguishing systems.
OTHER PRECAUTIONS Prohibit backfeed into containers.
RELEASE OR SPILL PROCEDURES Evacuate and ventilate the affected area. Prohibit general entry into areas where high concentrations may exist, particularly confined or poorly ventilated areas. Keep in mind that this product is denser than air and that concentrations will be higher at lower levels (sewers, basements or pits). Trained personnel should use self-contained breathing apparatus when entering areas where high concentrations may exist.
WASTE DISPOSAL Product can be reclaimed unless contaminated. Contact distributor to arrange reclamation. Otherwise, disposal should be in accordance with applicable law, generally by incineration at a qualified facility with an appropriate scrubber and other emission control technology.
SECTION VIII – SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION NIOSH/MSHA approved self-contained breathing apparatus for entry into areas where high concentrations may exist.
VENTILATION Passive ventilation (windows, doors, etc.) generally adequate for small areas. Mechanical ventilation for control of large areas and storage or filling facilities.
DERMAL PROTECTION Lined, neoprene gloves for handling liquid product.
EYE PROTECTION Shatterproof chemical splash goggles when handling liquid or working on pressurized containers.
OTHER PROTECTIVE EQUIPMENT Clothing to minimize contact with liquid product or at potential points of release.
OTHER PROTECTIVE PRACTICES Employ prudent confined space entry and related procedures (confirm equipment is free of product and has been ventilated, etc.). As with all chemical products, wash thoroughly after handling and wash contaminated clothing before re-use.
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM RATINGS
HEALTH = 1 FLAMMABILITY = 0 REACTIVITY = 0
HAZARD INDEX 0 = MINIMAL HAZARD, 1 = SLIGHT HAZARD, 2 = MODERATE HAZARD, 3 = SERIOUS HAZARD AND 4 = SEVERE HAZARD
SHIPPING INFORMATION – U.S. DOT GENERAL
DOT SHIPPING NAME HEPTAFLUOROPROPANE
DOT ID NUMBER UN3296
DOT HAZARD CLASS 2.2 NON-FLAMMABLE, COMPRESSED GAS
PACKING GROUP N/A
PACKAGING INSTRUCTIONS 200
SPECIAL PROVISIONS T50
NON-BULK PACKAGING 304
PASSENGER AIR/RAIL LIMIT 75 kg/package
AIR CARGO LIMIT 150 kg/package
VESSEL STOWAGE A
REPORTABLE QUANTITY None specified
LABEL NON-FLAMMABLE GAS
PACKAGING EXCEPTIONS 306
BULK PACKAGING 314/315
OTHER STOWAGE N/A
AIR TRANSPORT – ICAO OR IATA
PROPER SHIPPING NAME HEPTAFLUOROPROPANE
ID NUMBER UN3296
HAZARD CLASS 2.2 NON-FLAMMABLE, COMPRESSED GAS
SUBSIDIARY RISK N/A
PACKING GROUP N/A
PACKAGING INSTRUCTIONS 200
PACKAGING INSTRUCTIONS – CARGO 200
SPECIAL PROVISIONS N/A
AIR PASSENGER LIMIT 75 kg/package
AIR CARGO LIMIT 150 kg/package
LABEL NON-FLAMMABLE GAS
WATER – IMDG
PROPER SHIPPING NAME HEPTAFLUOROPROPANE
ID NUMBER UN3296
HAZARD CLASS 2.2 NON-FLAMMABLE, COMPRESSED GAS
SUBSIDIARY RISK N/A
PACKING GROUP N/A
MEDICAL/FIRST AID GUIDE N/A